In 2013, Alao got married to Wale Ajibola, her second husband, in the United States after her marriage to Dare Ogunlana hit the rocks in 2008.
“Glory be to Allah. Join me in congratulating Lola Alao (a popular Nollywood actress). She just took the Kalimatu Shaa’dah from me, and chose the name Rhodiat. May Allah give her proper understanding of Islam, and make her, well grounded in her new faith, Al-Islam. Aamiyn”, Yusuf wrote.